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The Clapeyron equation, derived in Sec 64 for the latent heat of phase transition of pure chemical species, is also applicable to pure-gas adsorption equilibrium Here, however, the two-phase equilibrium pressure depends not only on temperature, but on surface coverage or the amount adsorbed Thus the analogous equation for adsorption is written
would put a special border on the check box once it was set Other user-interface selectors are also defined under an emerging CSS3 UI specification,3 like :default, :valid, :invalid, :in-range, :out-of-range, :required, :optional, :read-only, and :read-write The meaning of some of these should be clear; for example,
LogMessage is a simple interface that declares one method, log( ), which takes a single String parameter This is used to abstract the output of messages from the httpd In the application case, this method is implemented to print to the standard output of the console in which the application was started In the applet case, the data is appended to a windowed text buffer The Code Here is the source code for LogMessage: interface LogMessage { public void log(String msg); }
input[type=text]:readonly {border: 2px dashed red;}
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where subscript n signifies that the derivative is taken at constant amount adsorbed Superscript av denotes a property change of desorption, ie, the difference between the vapor-phase and the adsorbed-phase property The quantity AH"" H U- H a is defined as the isosteric heat ofadsorption, and is usually a positive quantity28 The heat of adsorption is a useful indication of the strength of the forces binding adsorbed molecules to the surface of the adsorbent, and its magnitude can therefore often be used to distinguish between physical adsorption and chemisorption The dependence of heats of adsorption on surface coverage has its basis in the energetic heterogeneity of most solid surfaces The first sites on a surface to be occupied are those which attract adsorbate molecules most strongly and with the greatest release of energy Thus the heat of adsorption decreases with surface coverage Once all sites are occupied and multilayer adsorption begins, the dominant forces become those between adsorbate molecules, and for subcritical species the decreasing heat of adsorption approaches the heat of vaporization Assumed in the derivation of the Langmuir isotherm is the energetic equivalence of all adsorption sites, implying that the heat of adsorption is independent of surface coverage This explains in part the inability of the Langmuir isotherm to provide a close fit to most experimental data over a wide range of surface coverage The Freundlich isotherm, Eq (1411 I), implies a logarithmic decrease in the heat of adsorption with surface coverage As in the development of the Clausius/Clapeyron equation (Example 65), if for low pressures one assumes that the gas phase is ideal and that the adsorbate is of negligible volume
Part II:
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ASP . NET component that allows online Annotation of PDF files ...
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